SUBSTITUENT GROUP EFFECTS ON THE SELF-ASSEMBLY OF OXOVANADIUM(V) COMPLEXES WITH HYDRAZONE LIGANDS BEARING BENZOIC ACID (1-METHYL-3-OXOBUTYLIDENE)HYDRAZIDE BACKBONES

An oxo-bridgcd dinuclear oxovanadium(V) complex, [V2O2(µ-O)(L1)2] (1) [H2L1=3-nitrobenzoic acid (1-methyl-3-oxobutylidene)hydrazide], and a mononuclear oxovanadium(V) complex, [VO(OMe)(L2)] (2) [H2L2=3-hydroxynaphthalene-2-carboxylic acid (1-methyl-3-oxobutylidene)hydrazide], were prepared by the reactions of [VO(acac)2] with H2L1 and H2L2, respectively, in methanol.

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Тэги

hydrazone ligands oxovanadium(V) complex self-assembly substituent effects crystal structure.

Тематические рубрики

Прикладные науки. Медицина. Технология

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An oxo-bridgcd dinuclear oxovanadium(V) complex, [V2O2(µ-O)(L1)2] (1) [H2L1=3-nitrobenzoic acid (1-methyl-3-oxobutylidene)hydrazide], and a mononuclear oxovanadium(V) complex, [VO(OMe)(L2)] (2) [H2L2=3-hydroxynaphthalene-2-carboxylic acid (1-methyl-3-oxobutylidene)hydrazide], were prepared by the reactions of [VO(acac)2] with H2L1 and H2L2, respectively, in methanol.! <...> An oxo-bridgcd dinuclear oxovanadium(V) complex, [V2O2(µ-O)(L1)2] (1) [H2L1=3-nitrobenzoic acid (1-methyl-3-oxobutylidene)hydrazide], and a mononuclear oxovanadium(V) complex, [VO(OMe)(L2)] (2) [H2L2=3-hydroxynaphthalene-2-carboxylic acid (1-methyl-3-oxobutylidene)hydrazide], were prepared by the reactions of [VO(acac)2] with H2L1 and H2L2, respectively, in methanol.! <...>

** - вычисляется автоматически, возможны погрешности

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SUBSTITUENT GROUP EFFECTS ON THE SELF-ASSEMBLY OF OXOVANADIUM(V) COMPLEXES WITH HYDRAZONE LIGANDS BEARING BENZOIC ACID (1-METHYL-3-OXOBUTYLIDENE)HYDRAZIDE BACKBONES

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