РУсскоязычный Архив Электронных СТатей периодических изданий
Журнал Сибирского федерального университета. Химия. Journal of Siberian Federal University/ Chemistry/2015/№ 4/

The Properties of the Water-Soluble Hydroxy-Polyhydroxy fullerenes in Auto-Oxidation Reactions Epinephrine

The studied of the inяuence of fullerenoles on adrenaline auto-oxidation reaction by optical and theoretical methods was carried out in this work. It was shown that fullerenols at concentrations from 0.0005 mg/ml to 0.5 mg/ml exhibits prooxidant activity and accelerates autoxidation reaction of adrenaline. The suggested scheme of auto-oxidation reaction, which explained by energy advantage under transferring electron from the molecule of adrenaline to fullerenol by density functional method B3LYP/6-31(p,d).

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